潘晶晶, 薛振銮, 金志伟, 袁宇飞, 李波, 杨丽霞, 罗胜联. 烟草炭基材料的染料吸附行为研究[J]. 南昌航空大学学报(自然科学版), 2025, 39(5): 11-18, 30. DOI: 10.3969/j.issn.2096-8566.2025.05.002
引用本文: 潘晶晶, 薛振銮, 金志伟, 袁宇飞, 李波, 杨丽霞, 罗胜联. 烟草炭基材料的染料吸附行为研究[J]. 南昌航空大学学报(自然科学版), 2025, 39(5): 11-18, 30. DOI: 10.3969/j.issn.2096-8566.2025.05.002
Jingjing PAN, Zhenluan XUE, Zhiwei JIN, Yufei YUAN, Bo LI, Lixia YANG, Shenglian LUO. Research on Dye Adsorption Behavior of Tobacco Carbon-based Adsorbent[J]. Journal of nanchang hangkong university(Natural science edition), 2025, 39(5): 11-18, 30. DOI: 10.3969/j.issn.2096-8566.2025.05.002
Citation: Jingjing PAN, Zhenluan XUE, Zhiwei JIN, Yufei YUAN, Bo LI, Lixia YANG, Shenglian LUO. Research on Dye Adsorption Behavior of Tobacco Carbon-based Adsorbent[J]. Journal of nanchang hangkong university(Natural science edition), 2025, 39(5): 11-18, 30. DOI: 10.3969/j.issn.2096-8566.2025.05.002

烟草炭基材料的染料吸附行为研究

Research on Dye Adsorption Behavior of Tobacco Carbon-based Adsorbent

  • 摘要: 针对染料废水处理需求,本研究利用烟草废弃物制备高效吸附材料,以实现绿色治理。以烟草废弃物为原料,通过简单碳化和制孔策略制备烟草炭基吸附材料。利用紫外−可见分光光度计、傅里叶变换红外光谱和扫描电镜等仪器表征材料的物化性质和吸附行为。结果表明,KOH活化的吸附剂(AC@KOH)具有均匀的介孔结构(2.8614 nm)和高比表面积(1125.351 m2/g),比表面积比原始生物炭(AC)提高了210倍。AC@KOH对亚甲基蓝和罗丹明B的吸附量分别达到640.75、639.45 mg/g,吸附过程符合伪二级动力学,以化学吸附为主。AC@KOH的吸附机理主要包括配位作用、氢键作用、离子π或π-π作用、静电作用和物理孔道限域作用等。本研究成功制备高性能的烟草炭基吸附材料,可为低成本、可实际应用的染料废水绿色处理提供理论参考和设计思路。

     

    Abstract: In order to address the demands of dye wastewater treatment, high-efficiency adsorption materials were prepared from tobacco waste in this study. The tobacco-based carbon absorbent was prepared via a simple carbonization and pore-forming strategy with tobacco waste as the precursor. The physicochemical properties and adsorption behavior of the materials were characterized using instruments such as UV-Vis spectrophotometer, Fourier transform infrared spectroscopy, and scanning electron microscopy. The results indicate that the KOH- activated adsorbent (AC@KOH) possesses a uniform microporous structure (2.8614 nm) and a high specific surface area (1125.351 m2/g) which is 210 times higher than original unmodified biochar (AC). The adsorption capacity of AC@KOH for methylene blue and rhodamine B reaches 640.75 mg/g and 639.45 mg/g, respectively. The adsorption process is accorded with the pseudo-second-order kinetic model, predominantly involving chemical adsorption. The adsorption behavior of AC@KOH is governed by a synergistic effect of multiple interactions, including coordination, hydrogen bonding, ion-π or π-π interactions, electrostatic interactions, and physical pore confinement effects. This study successfully develops a high-performance tobacco-based carbon adsorbent, providing theoretical references and design insights for low-cost, practical green treatment of dye wastewater.

     

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