丁园, 肖亮亮, 谢青霞. 活性炭对不同土类复合污染土壤Cu的钝化阻控[J]. 南昌航空大学学报(自然科学版), 2017, 31(3): 78-83. DOI: 10.3969/j.issn.1001-4926.2017.03.013
引用本文: 丁园, 肖亮亮, 谢青霞. 活性炭对不同土类复合污染土壤Cu的钝化阻控[J]. 南昌航空大学学报(自然科学版), 2017, 31(3): 78-83. DOI: 10.3969/j.issn.1001-4926.2017.03.013
DING Yuan, XIAO Liang-liang, XIE Qing-xia. Stabilization Effects of Active Carbon on Copper in Different Combined Contaminated Soils[J]. Journal of nanchang hangkong university(Natural science edition), 2017, 31(3): 78-83. DOI: 10.3969/j.issn.1001-4926.2017.03.013
Citation: DING Yuan, XIAO Liang-liang, XIE Qing-xia. Stabilization Effects of Active Carbon on Copper in Different Combined Contaminated Soils[J]. Journal of nanchang hangkong university(Natural science edition), 2017, 31(3): 78-83. DOI: 10.3969/j.issn.1001-4926.2017.03.013

活性炭对不同土类复合污染土壤Cu的钝化阻控

Stabilization Effects of Active Carbon on Copper in Different Combined Contaminated Soils

  • 摘要: 采用一次平衡吸附实验,探讨活性炭对人工制备的赤红壤、黄壤、黄棕壤和红壤等4种单一/复合污染土壤Cu的固持效果,以期实现污染土壤的安全再利用。结果表明,对照单一污染土壤,复合污染土壤Cd与Cu产生协同作用,显著增加平衡液Cu的浓度。当活性炭的投加量为50 g/kg土时,活性炭对4种土壤Cu均可产生有效的固持作用,固持率在52%~74%之间,这主要是由于活性炭具有孔隙多、比表面积大、丰富的表面官能团。活性炭对污染土壤的修复效果还受有机质含量的影响,但受Cd的影响不大。

     

    Abstract: The stabilization effects of active carbon material on copper in copper and cadmium combined contaminated soils by static desorption experiment were discussed in order to realize the safe utilization of the soils. Four kinds of tested soils, iatosolic red soil, zheltozem, yellow brown soil and red soil namely, were prepared as sole/combined contaminated soils with chemical solvents. The results indicated there was significant synergy between copper and cadmium in combined contaminated soil, compared with sole contaminated soil. So the copper concentration in the balance solution in the combined contaminated soil was higher than that in sole contaminated soil. The stabilization rate of active carbon to copper was from 52% to 74% by static desorption experiments when the dose of carbon materials was both 5% of soil weight because active carbon was abundance of specific surface area and surface functional group. In addition, the stabilization results on copper were affected by the content of organic materials, not by cadmium.

     

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