崔霞, 周贤良, 欧阳德来, 宋龙飞, 汪松平. SiCp/Al复合材料用SiC表面预氧化处理研究[J]. 南昌航空大学学报(自然科学版), 2017, 31(2): 44-49. DOI: 10.3969/j.issn.1001-4926.2017.02.008
引用本文: 崔霞, 周贤良, 欧阳德来, 宋龙飞, 汪松平. SiCp/Al复合材料用SiC表面预氧化处理研究[J]. 南昌航空大学学报(自然科学版), 2017, 31(2): 44-49. DOI: 10.3969/j.issn.1001-4926.2017.02.008
CUI Xia, ZHOU Xian-liang, OUYANG De-lai, SONG Long-fei, WANG Song-ping. Study on Pre-oxidation Process of SiC Used in SiCp/Al Composites[J]. Journal of nanchang hangkong university(Natural science edition), 2017, 31(2): 44-49. DOI: 10.3969/j.issn.1001-4926.2017.02.008
Citation: CUI Xia, ZHOU Xian-liang, OUYANG De-lai, SONG Long-fei, WANG Song-ping. Study on Pre-oxidation Process of SiC Used in SiCp/Al Composites[J]. Journal of nanchang hangkong university(Natural science edition), 2017, 31(2): 44-49. DOI: 10.3969/j.issn.1001-4926.2017.02.008

SiCp/Al复合材料用SiC表面预氧化处理研究

Study on Pre-oxidation Process of SiC Used in SiCp/Al Composites

  • 摘要: 通过对SiC颗粒的高温氧化和增重实验,研究了SiC高温氧化规律和氧化动力学,探讨了SiC高温氧化后SiCp/Al复合材料的界面反应。结果表明,SiC颗粒氧化增重随氧化时间增加,先快速增加,后缓慢增加,符合抛物线规律。SiO2氧化膜厚度随加热温度升高而增加。氧化温度低于900℃时氧化速度较慢,超过1 300℃时氧化膜厚度随氧化温度增加而增加不明显,SiC颗粒表面氧化处理应以氧化温度为1 100℃和氧化时间为10 h为宜。SiC颗粒氧化处理可使SiCp/Al复合材料界面反应形成Al2O3界面相,而有效抑制了界面相Al4C3的产生。

     

    Abstract: The oxidation kinetics of SiC was investigated by oxidation process and oxidation mass gain test, and the interface reactions of SiCp/Al composites with pre-oxidated SiC particles were discussed. The results show that the oxidation weight gain increases rapidly, and then increases slowly with increasing oxidation time, which obeys the parabolic law. The oxidation rate of SiC increases with oxidation temperature, while the thickness of the oxide film is not significantly increased as the oxidation temperature is less than 900℃ or higher than 1 300℃. According to the effect of pre-oxidation, the oxidation temperature of 1 100℃ and the oxidation time of 10 h are preferable for pre-oxidation of SiC. Formation of the interface phase of Al2O3 in SiCp/Al composites with pre-oxidated SiC particles results in inhibiting the occurrence of the interface phase of Al4C3.

     

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