杨起, 胡德安, 程东海, 陈益平, 范东辰. Ni颗粒合金化对Sn58Bi钎料组织和性能的影响[J]. 南昌航空大学学报(自然科学版), 2017, 31(1): 55-60. DOI: 10.3969/j.issn.1001-4926.2017.01.009
引用本文: 杨起, 胡德安, 程东海, 陈益平, 范东辰. Ni颗粒合金化对Sn58Bi钎料组织和性能的影响[J]. 南昌航空大学学报(自然科学版), 2017, 31(1): 55-60. DOI: 10.3969/j.issn.1001-4926.2017.01.009
YANG Qi, HU De-an, CHENG Dong-hai, CHEN Yi-ping, FAN Dong-chen. Effect of Ni Particles Alloying on the Microstructure and Mechanical Properties of Sn58Bi[J]. Journal of nanchang hangkong university(Natural science edition), 2017, 31(1): 55-60. DOI: 10.3969/j.issn.1001-4926.2017.01.009
Citation: YANG Qi, HU De-an, CHENG Dong-hai, CHEN Yi-ping, FAN Dong-chen. Effect of Ni Particles Alloying on the Microstructure and Mechanical Properties of Sn58Bi[J]. Journal of nanchang hangkong university(Natural science edition), 2017, 31(1): 55-60. DOI: 10.3969/j.issn.1001-4926.2017.01.009

Ni颗粒合金化对Sn58Bi钎料组织和性能的影响

Effect of Ni Particles Alloying on the Microstructure and Mechanical Properties of Sn58Bi

  • 摘要: 针对Sn58Bi钎料组织和性能在时效阶段稳定性差的问题,研究了Ni (50 nm)颗粒合金化对时效阶段Sn58Bi钎料组织和性能的影响。研究结果表明:在时效反应阶段,复合钎料中会产生金属间化合物(IMC)阻挡层,抑制了Cu6Sn5向Cu3Sn的相变过程,使得Bi相无法再通过此相变过程而大量偏聚到钎缝结合处,从而提高了Sn58Bi-Ni钎料焊缝接头的组织稳定性能。当Sn58Bi钎料中添加的Ni颗粒后,Bi相的形核率得以提升,局部的钎料组织发生细化,纯Bi相和纯Sn相的偏聚被抑制,钎料内部组织时效稳定性能提高。当Ni质量分数约为0.5%时,在Sn58Bi-Ni复合钎料中组织及性能指标最佳。

     

    Abstract: In order to solve the problem of poor stability of the microstructure and mechanical properties of Sn58Bi welded joints in the aging stage, the effect of Ni particles (50 nm) alloying on the microstructure and mechanical properties of Sn58Bi welded joints is studied. The results of the study show that, in the aging reaction stage, IMC barrier layer will be generated in the composite solder, the phase transition of Cu6Sn5 to Cu3Sn is suppressed, which makes the Bi phase unable to segregate to the brazing junction through the phase change process, so that the microstructure stability of Sn58Bi-Ni solder welding seam is overall improved. With the addition of Ni particles in the Sn58Bi solder,the nucleation rate of Bi phase was improved, and the local microstructure of solder was refined, and the segregation of pure Bi and pure Sn phase was inhibited, and the stability of the internal structure of solder was improved. When the content of Ni is about 0.5wt%, the mechanical properties of Sn58Bi-Ni composite solder is the best.

     

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