杨起, 程东海, 胡德安, 陈益平, 范东辰. Cu颗粒对Sn58Bi接头钎缝组织的影响[J]. 南昌航空大学学报(自然科学版), 2016, 30(2): 74-78. DOI: 10.3969/j.issn.1001-4926.2016.02.012
引用本文: 杨起, 程东海, 胡德安, 陈益平, 范东辰. Cu颗粒对Sn58Bi接头钎缝组织的影响[J]. 南昌航空大学学报(自然科学版), 2016, 30(2): 74-78. DOI: 10.3969/j.issn.1001-4926.2016.02.012
YANG Qi, CHENG Dong-hai, HU De-an, CHEN Yi-ping, FAN Dong-chen. The Effects of Copper Particles on the Microstructure of Sn58Bi Soldered Joints[J]. Journal of nanchang hangkong university(Natural science edition), 2016, 30(2): 74-78. DOI: 10.3969/j.issn.1001-4926.2016.02.012
Citation: YANG Qi, CHENG Dong-hai, HU De-an, CHEN Yi-ping, FAN Dong-chen. The Effects of Copper Particles on the Microstructure of Sn58Bi Soldered Joints[J]. Journal of nanchang hangkong university(Natural science edition), 2016, 30(2): 74-78. DOI: 10.3969/j.issn.1001-4926.2016.02.012

Cu颗粒对Sn58Bi接头钎缝组织的影响

The Effects of Copper Particles on the Microstructure of Sn58Bi Soldered Joints

  • 摘要: 针对Cu颗粒(2 μm)对Sn58Bi接头钎缝组织和力学性能的影响规律进行了探讨和实验研究。研究结果表明:当Sn58Bi钎料中添加Cu颗粒含量ω(Cu)=0.3%~1.0%时,细小的颗粒钉扎在晶界附近,抑制了Sn58Bi系钎料的纯Bi相和纯Sn相偏聚。同时Cu颗粒和颗粒周围形成的金属间化合物Cu6Sn5有效促进Bi相的形核细化了Bi相组织,但ω(Cu)>1.0%时,由于颗粒钉扎在晶界附近Cu颗粒与钎料中的Sn接触面积倍增促使Cu6Sn5的量增多而导致其周围摩尔体积的增加,为了达到系统的平衡状态,富Bi区出现极细长易断裂的Bi相组织,造成钎焊接头的力学性能下降。在实验数据内,未时效条件下含Cu的钎料力学性能优于未含Cu的钎料。当ω(Cu)=0.5%,接头拉剪强度最终达到5种钎料中的最大值。

     

    Abstract: In the light of the effect of copper particles(2 μm) on the microstructure and mechanical properties of sn58Bi welded joints. The results show that when the content of copper particles in the Sn58Bi solder was ω(Cu)=0.3%~1.0%, the fine particles are pinned near the grain boundaries, which inhibits the pure Bi and pure Sn phase segregation of the Sn58Bi system. At the same time, copper particles and the intermetallic compound Cu6Sn5 around particles can effectively promote the nucleation of Bi phase and refine the microstructure of Bi phase. But when ω(Cu)>1.0%, because the fine particles are pinned near the grain boundaries, the contact area of the copper particles and the Sn in the solder multiply. It makes the amount of Cu6Sn5 increased and lead to the increase of the molar volume. In order to achieve the balance of the system, Bi phase structure which is extremely thin and easy to break occurs in the rich Bi region, it makes that the mechanical properties of the joints caused by brazing are decreased. In the experimental data range, the mechanical properties of the nonageing Cu containing solders are much better than those without copper. When ω(Cu)=0.5%, the maximum value of the joint tensile shear strength of five kinds is finally achieved.

     

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