Abstract: Based on the perspective of personal center, this paper takes 275 higher vocational teachers as the subjects in Jiangxi province, and uses SPSS to carry out cluster analysis, multiple variance analysis, logistic regression and other statistical researches. The results indicated that: Higher vocational teachers belong to the level of mild burnout, with a burnout rate of 58.2%. There are three types of professional values in higher vocational teachers: survival type (14.9%), common type (65.8%), development type (19.3%). Teachers with developmental professional values have the lowest level of burnout, and the incidence of burnout is only 45.1% of that of survival teachers.There are significant differences in the types of professional values among teachers with different individual characteristics. According to the results of empirical research, this paper puts forward some suggestions on the establishment of positive professional values from both schools and individuals.