路福叶,欧阳翼龙,王誉龙,等. 锡基焊料合金的电化学迁移失效研究进展[J]. 失效分析与预防,2026,21(4):295-304,346. doi: 10.3969/j.issn.1673-6214.2026.04.002
    引用本文: 路福叶,欧阳翼龙,王誉龙,等. 锡基焊料合金的电化学迁移失效研究进展[J]. 失效分析与预防,2026,21(4):295-304,346. doi: 10.3969/j.issn.1673-6214.2026.04.002
    LU Fuye,OUYANG Yilong,WANG Yulong,et al. Research progress on electrochemical migration failure of tin-based solder alloys[J]. Failure analysis and prevention,2026,21(4):295-304,346. doi: 10.3969/j.issn.1673-6214.2026.04.002
    Citation: LU Fuye,OUYANG Yilong,WANG Yulong,et al. Research progress on electrochemical migration failure of tin-based solder alloys[J]. Failure analysis and prevention,2026,21(4):295-304,346. doi: 10.3969/j.issn.1673-6214.2026.04.002

    锡基焊料合金的电化学迁移失效研究进展

    Research Progress on Electrochemical Migration Failure of Tin-based Solder Alloys

    • 摘要: 随着电子封装技术向高密度集成与微间距互连方向发展,焊点间距的急剧缩减导致局部电场强度显著增大,在环境湿气与离子污染物的共同作用下引发电化学迁移(ECM)失效,严重威胁电子设备的长期服役可靠性。本文首先概述了ECM的基本原理,对比分析了导电阳极丝与枝晶生长两种失效模式的机理差异,并总结了温湿偏置试验与水滴试验等常用研究方法的优缺点;随后重点探讨了偏置电压、尘土污染物、助焊剂残留及合金成分等关键因素对焊料合金阳极溶解、离子迁移及枝晶生长行为的影响规律;最后总结了抑制锡基焊料电化学迁移的可行策略,包括合金化改性、缓蚀剂添加及脉冲或交流电压调控等,并结合当前研究现状对该领域未来的研究重点与发展趋势进行了展望。

       

      Abstract: With the rapid advancement of electronic packaging technology toward high-density integration and fine-pitch interconnection, the drastic reduction in solder joint spacing leads to a significant increase in local electric field strength. Under the combined influence of environmental moisture and ionic contaminants, electrochemical migration (ECM) failure is readily triggered, posing a serious threat to the long-term service reliability of electronic devices. This paper first outlines the fundamental mechanism of ECM, compares the mechanistic differences between conductive anodic filament growth and dendrite formation, and summarizes the advantages and limitations of commonly used accelerated testing methods such as temperature-humidity bias testing and the water drop test. Subsequently, the effects of key factors including bias voltage, dust contaminants, flux residue, and alloy composition on the anodic dissolution, ion migration, and dendrite growth behavior of solder alloys are discussed in detail. Finally, the paper summarizes feasible strategies for suppressing the electrochemical migration of tin (Sn)-based solders, including alloy modification, the addition of corrosion inhibitors, and the use of pulsed or alternating voltage regulation. It also provides an outlook on future research priorities and trends in this field based on the current state of knowledge.

       

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