宋阁,汤姣,曹奔,等. SiC-CMC陶瓷基复合材料火焰筒环境障涂层失效机理分析[J]. 失效分析与预防,2025,20(4):308-316. doi: 10.3969/j.issn.1673-6214.2025.04.007
    引用本文: 宋阁,汤姣,曹奔,等. SiC-CMC陶瓷基复合材料火焰筒环境障涂层失效机理分析[J]. 失效分析与预防,2025,20(4):308-316. doi: 10.3969/j.issn.1673-6214.2025.04.007
    SONG Ge,TANG Jiao,CAO Ben,et al. Failure mechanism of environmental barrier coatings on SiC-CMC ceramic composite combustion chamber[J]. Failure analysis and prevention,2025,20(4):308-316. doi: 10.3969/j.issn.1673-6214.2025.04.007
    Citation: SONG Ge,TANG Jiao,CAO Ben,et al. Failure mechanism of environmental barrier coatings on SiC-CMC ceramic composite combustion chamber[J]. Failure analysis and prevention,2025,20(4):308-316. doi: 10.3969/j.issn.1673-6214.2025.04.007

    SiC-CMC陶瓷基复合材料火焰筒环境障涂层失效机理分析

    Failure Mechanism of Environmental Barrier Coatings on SiC-CMC Ceramic Composite Combustion Chamber

    • 摘要: 发动机在服役环境下,其碳化硅纤维增强的碳化硅陶瓷基复合材料(SiC-CMC)易发生高温水氧腐蚀。针对SiC-CMC基体表面的环境障涂层(EBCs)开展台架试验研究,在最高火焰温度超过1700 ℃的条件下,观察到火焰筒局部EBCs出现熔化和脱落现象,并出现不同形状的Si液滴。通过对火焰筒烧蚀情况进行分析,揭示了EBCs的失效机理并提出相应改进措施。结果表明:火焰筒基体温度达到1450~1500 ℃,超过涂层的使用温度;火焰筒基体热导率偏低,导致火焰筒的散热效果较差和热应力集中,火焰筒基体温度超过涂层使用温度极限。采用复合工艺提高CVI-CMC复合材料的致密度和提高热导率,可将孔隙率降低到5%以下,并使高温热导率提升至15 W/(m·K)以上,从而有效延长部件的使用寿命。

       

      Abstract: Under the service environment of the engine, the silicon carbide fiber-reinforced silicon carbide ceramic matrix composite material (SiC-CMC) experiences high-temperature water oxygen corrosion failure. The environmental barrier coatings (EBCs) on the surface of SiC-CMC substrate were subjected to bench testing, and the highest flame temperature was above 1700 ℃. It was observed that the local melting and peeling of the EBCs and the Si droplets of different shapes appeared on the burner. The failure mechanism of EBCs was revealed and corresponding improvement measures were proposed through analyzing the erosion situation of the burner. The results show that the temperature of the burner substrate reaches 1450~1500 ℃, exceeding the operating temperature of the coating; The low thermal conductivity of the burner substrate results in poor heat dissipation and thermal stress concentration, which may cause the temperature of the burner substrate to exceed the operating temperature limit of EBCs. By using composite processes to improve the density and thermal conductivity of CVI-CMC composite materials, the porosity is reduced to below 5%, and the thermal conductivity at high temperatures is increased to over 15 W/(m·K), which can significantly extend the service life of the components.

       

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