邱小林, 邱震钰. 石墨烯掺杂对镁锂合金微弧氧化膜Cl腐蚀敏感性的研究[J]. 失效分析与预防, 2019, 14(2): 106-110. DOI: 10.3969/j.issn.1673-6214.2019.02.007
    引用本文: 邱小林, 邱震钰. 石墨烯掺杂对镁锂合金微弧氧化膜Cl腐蚀敏感性的研究[J]. 失效分析与预防, 2019, 14(2): 106-110. DOI: 10.3969/j.issn.1673-6214.2019.02.007
    QIU Xiao-lin, QIU Zhen-yu. Corrosion Sensitivity of Graphene Doped Micro-arc Oxidation Film of Magnesium-lithium Alloy in Cl Solution[J]. Failure Analysis and Prevention, 2019, 14(2): 106-110. DOI: 10.3969/j.issn.1673-6214.2019.02.007
    Citation: QIU Xiao-lin, QIU Zhen-yu. Corrosion Sensitivity of Graphene Doped Micro-arc Oxidation Film of Magnesium-lithium Alloy in Cl Solution[J]. Failure Analysis and Prevention, 2019, 14(2): 106-110. DOI: 10.3969/j.issn.1673-6214.2019.02.007

    石墨烯掺杂对镁锂合金微弧氧化膜Cl腐蚀敏感性的研究

    Corrosion Sensitivity of Graphene Doped Micro-arc Oxidation Film of Magnesium-lithium Alloy in Cl Solution

    • 摘要: 为了研究添加石墨烯后镁锂合金微弧氧化膜在不同NaCl浓度下的腐蚀行为,通过向硅酸盐体系电解液中添加石墨烯,在镁锂合金表面制备出改性的MAO(Micro-arc oxidation)膜层,采用电化学极化曲线和阻抗谱方法研究改性膜层对NaCl溶液的腐蚀敏感性。结果表明:石墨烯的添加可有效改善由于微弧放电形成的孔洞及微裂纹等缺陷,提高膜层致密性和耐蚀性;改性的MAO膜层耐腐蚀性能随着NaCl溶液浓度的升高而降低,主要因为在较高的浓度梯度作用下,侵蚀性离子向膜层中扩散速率加快,进而加速了对MAO膜层的腐蚀破坏。

       

      Abstract: In order to find out the effect of graphene on the corrosion sensitivity of micro-arc oxidation (MAO) film of magnesium-lithium alloys, a modified MAO film was prepared on the surface of magnesium-lithium alloy by adding graphene to the electrolyte of silicate system. The electrochemical susceptibility of the modified film in NaCl solution of different concentration was studied by electrochemical polarization and electrochemical impedance spectrum methods. The results show that the addition of graphene can effectively improve the pores, micro-cracks and other defects due to micro-arc discharge, and improve the film density and corrosion resistance. The corrosion resistance of the modified MAO film decreases with the concentration of NaCl solution increasing. It is mainly due to the accelerated diffusion of aggressive ions into the film under the action of higher concentration gradient, accelerating the corrosion of the MAO film.

       

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